In this talk I will review the basic ingredients which allows one to formulate 10D super-Yang-Mills on pure spinor superspace. The respective pure spinor master action in the gauge b_{0}V = QΞ, will then be used to show that tree-level scattering amplitudes calculated via perturbiner methods, match those obtained from pure spinor CFT techniques. I will also discuss how to compute pure spinor kinematic numerators through the use of standard Feynman rules, and show these are described by compact expressions involving the b-ghost operator. Remarkably, it will be shown how color-kinematics duality immediately emerges in this pure spinor framework after imposing the Siegel gauge condition b_{0}V = 0. [for zoom link please contact h(dot)jiang(at)qmul(dot)ac(dot)uk]